Pyrolysis of Acetonitrile. (Part. I)

Pyrolysis of Tobacco Residue: Part 1. Thermal

The pyrolysis of two types of tobacco residue was carried out at different pyrolysis temperatures between 300 and 600 °C and a residence time of 1 h in a nitrogen atmosphere. The effect of pyrolysis temperature on the product distributions was investigated and the composition of the bio-oils identified. The variation in product distribution depended on both the temperature and the type of tobac...

Iodidotris(triphenyl­phosphine)copper(I) acetonitrile solvate

The title compound, [CuI(C(18)H(15)P)(3)]·C(2)H(3)N, was obtained from the reaction of triphenyl-phosphine and copper(I) iodide in acetonitrile. The monomeric form of the complex has slightly distorted coordination of Cu by the I atom and three P atoms. The crystal structure is stabilized by C-H⋯π inter-actions between phenyl H atoms and phenyl rings. In addition, the complex mol-ecules exhibit...

Poly[[(acetonitrile)­lithium(I)]-μ3-tetra­fluoridoborato]

The structure of the title compound, [Li(BF(4))(CH(3)CN)](n), consists of a layered arrangement parallel to (100) in which the Li(+) cations are coordinated by three F atoms from three tetra-fluoridoborate (BF(4) (-)) anions and an N atom from an acetonitrile mol-ecule. The BF(4) (-) anion is coordinated to three different Li(+) cations though three F atoms. The structure can be described as be...

Part] I I

[μ-Bis(diphenyl­phosphan­yl)acetonitrile-κ2 P:P]bis­[chloridogold(I)]

The title complex, [Au(2)Cl(2)(C(26)H(21)NP(2))], has an intra-molecular Au⋯Au inter-action of 3.1669 (4) Å, but no inter-molecular Au⋯Au inter-actions in the solid state. The Cl-Au-P bond angle of 176.84 (7)° is slightly distorted from linearity. The P-C bond length to the phenyl group is shorter [1.810 (7) Å] than the P-C bond length [1.876 (7) Å] to the bridging carbon, indicative of the fle...